Analog soil organo–ferrihydrite composites as suitable amendments for cadmium and arsenic stabilization in co-contaminated soils

Remediation of CdAs co-contaminated soils has long been considered a difficult problem to solve, as Cd and As have distinctly different metallic characters. Amending contaminated soils with traditional single passivation materials may not always work well in the stabilization of both Cd and As. Here, we reported that analog soil organo–ferrihydrite composites made with either living or non-living organics (bacterial cells or humic acid) could achieve stabilization of both Cd and As in contaminated soils. BCR and Wenzel sequential extractions showed that organo–ferrihydrite, particularly at 1 wt% loading, shifted liable Cd and As to more stable phases. Organo–ferrihydrite amendments significantly (p