Electrochemical Dearomative Spirocyclization

Electrochemical Dearomative Spirocyclization

Electrochemical dearomative spirocyclization serves as a green and sustainable approach to convert the flat, two‐dimension aromatic feedstock into the value‐added three‐dimension spirocyclic architectures. This review highlights the recent advances, emphasizes mechanistic discussions, and showcases...

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Veröffentlicht in:Chemistry, an Asian journal an Asian journal, 2023-05, Vol.18 (9), p.e202300122-n/a
Hauptverfasser: Li, Nan, Shi, Zhaojiang, Wang, Wei‐Zhen, Yuan, Yaofeng, Ye, Ke‐Yin
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
continuous-flow electrolysis
dearomative
electrochemistry
natural products
spirocyclic compounds
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Zusammenfassung:Electrochemical dearomative spirocyclization serves as a green and sustainable approach to convert the flat, two‐dimension aromatic feedstock into the value‐added three‐dimension spirocyclic architectures. This review highlights the recent advances, emphasizes mechanistic discussions, and showcases synthetic applications of this emerging versatile and powerful transformation. Recent advances in electrochemical dearomative spirocyclization, including reaction development, mechanistic investigations, and synthetic applications, are highlighted.
ISSN:1861-4728
1861-471X
DOI:10.1002/asia.202300122