Two Unprecedented Reactions of Nitrosyl Triflate: NO+‑Induced Cationic Cascade Cyclization and CC Oxidative Cleavage
Nitrosyl triflate is shown to react with olefins in a CH2Cl2 solution by three different pathways depending on structure and reaction conditions: (1) cationic cyclization, (2) CC cleavage, and (3) allylic nitrosation. Possible reaction pathways are described.
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| Veröffentlicht in: | Organic letters 2023-03, Vol.25 (11), p.1872-1877 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Nitrosyl triflate is shown to react with olefins in a CH2Cl2 solution by three different pathways depending on structure and reaction conditions: (1) cationic cyclization, (2) CC cleavage, and (3) allylic nitrosation. Possible reaction pathways are described. |
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| ISSN: | 1523-7060 1523-7052 |
| DOI: | 10.1021/acs.orglett.3c00353 |