Three-dimensional distribution characteristics of multiple pollutants in the soil at a steelworks mega-site based on multi-source information

Soil pollution at steelworks mega-sites has become a severe environmental issue worldwide. However, due to the complex production processes and hydrogeology, the soil pollution distribution at steelworks is still unclear. This study scientifically cognized the distribution characteristics of polycyclic aromatic hydrocarbons (PAHs), volatile organic compounds (VOCs), and heavy metals (HMs) at a steelworks mega-site based on multi-source information. Specifically, firstly, 3D distribution and spatial autocorrelation of pollutants were obtained by interpolation model and local indicators of spatial associations (LISA), respectively. Secondly, the characteristics of horizontal distribution, vertical distribution, and spatial autocorrelations of pollutants were identified by combining multi-source information such as production processes, soil layers, and properties of pollutants. Horizontal distribution showed that soil pollution in steelworks mainly occurred in the front end of the steel process chain. Over 47% of PAHs and VOCs pollution area were distributed in coking plants and over 69% of HMs in stockyards. Vertical distribution indicated that HMs, PAHs, and VOCs were enriched in the fill, silt, and clay layers, respectively. Spatial autocorrelation of pollutants was positively correlated with their mobility. This study clarified the soil pollution characteristics at steelworks mega-sites, which can support the investigation and remediation of steelworks mega-sites. [Display omitted] •We scientifically cognized the distribution characteristics of steelworks mega-sites.•Soil pollution in steelworks mainly occurred in the front end of steel process chain.•Organic pollution and HMs were observed in coking plant and stockyard, respectively.•HMs, PAHs, and VOCs in Luvisols enrich in fill, silt, and clay layers, respectively.•The mobility of pollutants positively correlated with their spatial autocorrelation.