Modified UiO-66-Br Microphotocatalyst with High Electron Mobility Enhances Tetracycline Degradation

In this work, the Br functional group on the ligand UiO-66-Br was modified with a Bi–O bond through the secondary solvothermal method, and the synthesis method of visible light catalyst UB (UiO-66-BiOBr) with high electron mobility was explored. The findings indicate that the effective charge transf...

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Veröffentlicht in:Langmuir 2023-03, Vol.39 (10), p.3678-3691
Hauptverfasser: Wei, Lihong, Zhang, Yao, Jiang, Jinyuan, Yang, Yinbo, Liu, Hui
Format: Artikel
Sprache:eng
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Zusammenfassung:In this work, the Br functional group on the ligand UiO-66-Br was modified with a Bi–O bond through the secondary solvothermal method, and the synthesis method of visible light catalyst UB (UiO-66-BiOBr) with high electron mobility was explored. The findings indicate that the effective charge transfer of the functional group-modified material UB is 2.98 times and 1.22 times that of BiOBr and traditional UiO-66/BiOBr heterojunctions, respectively. Under simulated sunlight irradiation, the removal rate of tetracycline can reach 88.71%, and the photocatalytic performance is 22.73 times higher than that of UiO-66-Br. Moreover, it maintains good adsorption and photocatalytic performance under different laboratory and actual engineering water environment conditions. In the complex water environment of municipal wastewater, the degradation effect reaches more than 80%. Finally, the decomposition pathways of TC and ecotoxicities of the intermediates were analyzed via combining theoretical calculation, LC–MS/MS, and T.E.S.T.
ISSN:0743-7463
1520-5827
DOI:10.1021/acs.langmuir.2c03308