Structure of poly(ethylene oxide) (PEO and PEO times LiSO sub(3)CF sub(3)) studied with spin polarised neutrons

Over the last two decades, poly(ethylene oxide) (PEO), one of the model solid polymer electrolytes, has been investigated by various techniques. Neutron scattering using spin polarised neutrons with spin polarisation analysis provides a unique opportunity to study both the structure and dynamics in the same experiment. This is feasible due to the experimental separation of the coherent and incoherent scattering, and it gives increased confidence in the models proposed. Using this technique, we studied PEO complexed with lithium triflate, LiSO sub(3)CF sub(3), at different concentrations, below and above T sub(g ). PEO below its glass transition has a strong tendency to crystallise, and even above T sub(g), displays considerable short-range order. In turn, this affects the analysis of the dynamics of the matrix (hence conductivity). The results obtained are compared with those obtained by others. copyright 2002 Elsevier Science B.V. All rights reserved.