Visible-light-induced Csp3–H functionalization of glycine derivatives by cerium catalysis

A Ce(iii)-catalyzed, visible-light-induced aerobic oxidative dehydrogenative coupling/aromatization reaction between glycine derivatives and alkenes has been developed, which provides an efficient approach for the synthesis of quinoline derivatives and post-modification of oligopeptides containing g...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2023-02, Vol.59 (18), p.2628-2631
Hauptverfasser: Wang, Shutao, Ye, Yanjie, Hu, Yansong, Xu, Meng, Liu, Zhao, Liu, Jiyu, Chen, Kuan, Zhang, Zhengze, Zhang, Yuan
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Sprache:eng
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Zusammenfassung:A Ce(iii)-catalyzed, visible-light-induced aerobic oxidative dehydrogenative coupling/aromatization reaction between glycine derivatives and alkenes has been developed, which provides an efficient approach for the synthesis of quinoline derivatives and post-modification of oligopeptides containing glycine residues under mild conditions without the need for external photosensitizers.
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc07071e