Rheological properties of ionically and covalently crosslinked polypropylene-type thermoplastic elastomers

Maleic anhydride was grafted onto a polypropylene‐type thermoplastic elastomer PER by reactive processing with a screw extruder, and a maleated PER (MPER) was prepared. Aiming at ionic crosslinking, magnesium 12‐hydroxy stearate (MgStOH), zinc oxide (ZnO), and zinc sulfide (ZnS), and aiming at covalent crosslinking, melamine as an amino compound, and Epocizer and GRYCI‐ALE as epoxy compounds, were added to the MPER, melt‐mixed by use of the screw extruder, and crosslinked compounds were obtained. The rheological properties such as capillary flow properties and dynamic viscoelasticities of the compounds were measured and their melt processabilities were evaluated. The degree of crosslinking was in the order of epoxy compounds > MgStOH > melamine > ZnO, ZnS > MPER (blank). In the case of the compound with MgStOH of a moderately high degree of crosslinking, the non‐Newtonian behavior is remarkable and the die swell ratio is low and suitable for extrusion. However, in the case of compounds with epoxy compounds of an excessive degree of crosslinking, fine extrudate cannot be obtained due to the lack of fusion and the control of degree of crosslinking is necessary. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 762–773, 2002