Benzophenone-containing phosphors with an unprecedented long lifetime of 1.8 s under ambient conditions

It is well-known that benzophenone has a short phosphorescence lifetime of around 1 ms even at 77 K. Here we report a benzophenone-containing emitter with an unprecedented long phosphorescence lifetime of 1.8 s under ambient conditions, which can be attributed to its T 1 state of localized excitatio...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2023-02, Vol.59 (11), p.1525-1528
Hauptverfasser: Su, Yuming, Wu, Minjian, Wang, Guangming, Li, Jiuyang, Chen, Xuefeng, Li, Xun, Wang, Guoxiang, Zhang, Kaka
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Sprache:eng
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Zusammenfassung:It is well-known that benzophenone has a short phosphorescence lifetime of around 1 ms even at 77 K. Here we report a benzophenone-containing emitter with an unprecedented long phosphorescence lifetime of 1.8 s under ambient conditions, which can be attributed to its T 1 state of localized excitation nature as revealed by detailed studies. Unlike benzophenone's phosphorescence lifetime of around 1 ms at 77 K, here the benzophenone-containing phosphor exhibits an ambient lifetime of 1.8 s.
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc06601g