Analysis of the multi-media environmental behavior of polycyclic aromatic hydrocarbons (PAHs) within Haizhou Bay using a fugacity model

In this study, we aimed to quantify the transport and fate of PAHs in different environmental phases (air, seawater, soil, sediment and fish), verify application of the Level III fugacity model in a bay simulation, and understand the transport and fate of PAHs in the bay environment on a macroscopic scale. The simulated average concentrations of ∑16PAH in the air and soil (23.8 ng/m3 and 1080.91 ng/g, respectively), which is as a background reference data for the Haizhou Bay. In addition, the soil (307 t), fish (29.4 t), and sediment (9.72 t) phases were found to be important reservoirs in the Haizhou Bay. Emissions from road vehicles (658 t) accounted for the largest share of PAH emissions in the area, and atmospheric deposition contributed most to the input of PAHs to the polluted area in the region. Whereas the contribution of river runoff input was small, and degradation loss was the main output pathway. [Display omitted] •A fugacity model was used to study fate of PAHs in Haizhou Bay.•Road vehicle source emissions contributed the most to PAH emissions in the region.•Organisms and sediment served as the greatest sinks for PAHs in Haizhou Bay.•HMW-PAHs were dominant in multicompartments.•Temperature was the most influential parameter for the model output.