Chronology of PAH and PCB pollution using sediment core in the Golden Horn estuary (Sea of Marmara)

The sources and depositional history of 16 polycyclic aromatic hydrocarbons (PAHs) and 18 polychlorinated biphenyl (PCBs) congeners in the Golden Horn estuary (İstanbul) were investigated using a dated sediment core for the period between 1880 and 2012. The concentrations of PAHs and PCBs were calculated for every 4 cm slices of the sediment core and ranged from 1203.5 to 3441.4 ng/g and 5.4 to 41.4 ng/g, respectively. The diagnostic ratios indicated that the maximum PAH values correspondence to combustion after a crude oil-carrying Romanian tanker (Independenta) accident in the İstanbul Strait in 1979. The historical deposition of PAHs and PCBs in the Golden Horn was influenced by municipal effluent and heavy industrial dischargers approximately 50 years. When the Silahtarağa thermal power plant (TPP) was operating, PCB pollution rose; however, after a thorough rehabilitation effort and the outlawing of PCB use in the 1990s, pollution levels significantly tended to decrease. •Rapid population growth triggered PAH and PCB pollution in Golden Horn, İstanbul.•Golden Horn sediment still bears the traces of Independenta accident since 1979.•PAH sources of the Golden Horn were identified as pyrogenic.•PCB concentrations decreased in core sediment, immediately after their ban.