The analysis of glass from portable electronic devices and glass accessories using µ-XRF for forensic investigations

In this study, glass from 30 different portable electronic devices (PED) screens, 15 screen protectors (SP), and 3 brands of liquid glass (LG) were analyzed using a µ-XRF instrument equipped with two silicon drift detectors (SDD). Additional analysis of six fragments, all originating from the same PED and SP screen, assessed the elemental homogeneity within a single glass source. Examinations of the 30 PEDs and the majority of the SP screens revealed spectra with low sodium and high potassium, which is likely due to the ion exchange process at the surface during the glass manufacturing process. The absence of calcium in the XRF spectra was also characteristic of PED formulations. Initial spectral overlay examinations classified the PED and SP samples into major groups based on their distinctive elemental profiles (5 PED groups, 4 SP groups). Further discrimination of within-group samples was possible when considering reproducible differences in signal intensities (discrimination 98.4 % PED, 98.1 % SP). Additionally, a 3 s (3 % Relative Standard Deviation, RSD) comparison criterion produced the lowest false exclusion rates among same-source fragments (3.3 % PED, 0.8 % SP) while maintaining a high discrimination power among different-source fragments (98.4 % PED, 100 % SP). Same source PED and SP samples resulted in low variability within most elements examined (