Regulating Spin States in Oxygen Electrocatalysis

Developing efficient and stable transition metal oxides catalysts for energy conversion processes such as oxygen evolution reaction and oxygen reduction reaction is one of the key measures to solve the problem of energy shortage. The spin state of transition metal oxides is strongly correlated with their catalytic activities. In an octahedral structure of transition metal oxides, the spin state of active centers could be regulated by adjusting the splitting energy and the electron pairing energy. Regulating spin state of active centers could directly modulate the d orbitals occupancy, which influence the strength of metal‐ligand bonds and the adsorption behavior of the intermediates. In this review, we clarified the significance of regulating spin state of the active centers. Subsequently, we discussed several characterization technologies for spin state and some recent strategies to regulate the spin state of the active centers. Finally, we put forward some views on the future research direction of this vital field. The spin state of transition metal oxides is strongly correlated with their catalytic activities. Regulating spin state of active centers could influence the strength of metal‐ligand bonds and the adsorption behavior of the intermediates. This minireview summarizes approaches for the characterization and regulation of spin states as a basis for the design of high‐performance electrocatalysts.