Electrical characteristics and annealing study of boron-doped polycrystalline diamond films

In this study, annealing was applied to as-grown boron-doped diamond films. The current-voltage (I-V) characteristics of the Al /boron-doped diamond films were also investigated. The conductivity of films was examined to determine the effect of annealing on boron-doped diamond films. Experimental re...

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Veröffentlicht in:Journal of the Electrochemical Society 1995, Vol.142 (12), p.L223-L225
Hauptverfasser: SHENG-HSIUNG CHEN, SHEN-LI CHEN, MING-HSING TSAI, SHYU, J. J, CHIA-FU CHEN
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container_end_page L225
container_issue 12
container_start_page L223
container_title Journal of the Electrochemical Society
container_volume 142
creator SHENG-HSIUNG CHEN
SHEN-LI CHEN
MING-HSING TSAI
SHYU, J. J
CHIA-FU CHEN
description In this study, annealing was applied to as-grown boron-doped diamond films. The current-voltage (I-V) characteristics of the Al /boron-doped diamond films were also investigated. The conductivity of films was examined to determine the effect of annealing on boron-doped diamond films. Experimental results indicated that the activation energy for the as-deposited diamond films (intrinsic or light boron-doped) is about 0.38 eV. After annealing, the activation energy did not change. However, the activation energy of the heavily doped films changed remarkably to 0.014 eV after annealing. FTIR and cathodoluminescence were performed to understand more clearly the correlation between the activation energy and the annealing effect on B-doped diamond films. These results revealed that for the lightly B-doped films, the boron atoms were effectively activated at the substitutional site. For the heavily doped case, boron was initially located in an inactive site (e.g., grain boundary, interstitial or clustering sites) and would diffuse into the substitutional site after annealing at 900 C. 20 refs.
doi_str_mv 10.1149/1.2048504
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However, the activation energy of the heavily doped films changed remarkably to 0.014 eV after annealing. FTIR and cathodoluminescence were performed to understand more clearly the correlation between the activation energy and the annealing effect on B-doped diamond films. These results revealed that for the lightly B-doped films, the boron atoms were effectively activated at the substitutional site. For the heavily doped case, boron was initially located in an inactive site (e.g., grain boundary, interstitial or clustering sites) and would diffuse into the substitutional site after annealing at 900 C. 20 refs.</abstract><cop>Pennington, NJ</cop><pub>Electrochemical Society</pub><doi>10.1149/1.2048504</doi></addata></record>
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subjects Cathodoluminescence, ionoluminescence
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Condensed matter: structure, mechanical and thermal properties
Defects and impurities in crystals
microstructure
Doping and impurity implantation in iii-v and ii-vi semiconductors
Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures
Electronic transport phenomena in thin films and low-dimensional structures
Exact sciences and technology
Low-field transport and mobility
piezoresistance
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
Other luminescence and radiative recombination
Physics
Structure of solids and liquids
crystallography
title Electrical characteristics and annealing study of boron-doped polycrystalline diamond films
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