Ostwald ripening in non-spherical morphologies

A statistical theory of Ostwald ripening has been extended to describe the diffusion-limited coarsening of non-spherical convex interfaces. Distributional analysis is performed on a series of interfacial patches, where the patches and adjacent isopotential surfaces have a common fixed ratio of princ...

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Veröffentlicht in:Materials science & engineering. A, Structural materials : properties, microstructure and processing Structural materials : properties, microstructure and processing, 1997-10, Vol.238 (1), p.140-147
Hauptverfasser: Marsh, S.P., Glicksman, M.E.
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Sprache:eng
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Zusammenfassung:A statistical theory of Ostwald ripening has been extended to describe the diffusion-limited coarsening of non-spherical convex interfaces. Distributional analysis is performed on a series of interfacial patches, where the patches and adjacent isopotential surfaces have a common fixed ratio of principal curvatures. Results of this analysis are expressed in terms of a dimensionless shape factor that ranges from zero for spherical interfaces to unity for cylindrical surfaces. Coarsening rate constants are calculated as a function of both the precipitate volume fraction and this geometric shape factor. Application of these results to ripening of ellipsoidal precipitates and other morphologies are discussed.
ISSN:0921-5093
1873-4936
DOI:10.1016/S0921-5093(97)00440-1