Seasonal variation and sources of atmospheric polycyclic aromatic hydrocarbons in a background site on the Tibetan Plateau

•PAHs is significantly affected by atmospheric temperature and relative humidity.•PAHs is moderate on the Tibetan Plateau and provides a useful background level.•PAHs mainly comes from coal and biomass combustion and vehicle emissions, with seasonal differences. The study of atmospheric polycyclic a...

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Veröffentlicht in:Journal of environmental sciences (China) 2023-03, Vol.125, p.524-532
Hauptverfasser: Wu, Xuemei, Sun, Weijun, Huai, Baojuan, Wang, Lei, Han, Chuntan, Wang, Yetang, Mi, Wenying
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Sprache:eng
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Zusammenfassung:•PAHs is significantly affected by atmospheric temperature and relative humidity.•PAHs is moderate on the Tibetan Plateau and provides a useful background level.•PAHs mainly comes from coal and biomass combustion and vehicle emissions, with seasonal differences. The study of atmospheric polycyclic aromatic hydrocarbons (PAHs) in northeastern Tibetan Plateau with fragile ecological environment and complex atmospheric circulation system is blank. To understand the characteristics and sources of persistent organic pollutants in the atmosphere of the northeastern Tibetan Plateau, we monitored levels in the central Qilian Mountain. From 2016 to 2017, we collected 45-pair (particle + gas) samples using active air samplers to investigate the sources, transport paths, and their influencing factors. Sources of PAHs were analysed with a source diagnostic model, and atmospheric transport paths were calculated. The concentration range for ∑15PAHs was 439–4666 pg/m3, and the average was 2015 pg/m3. The PAHs in central Qilian Mountain are mainly low molecular weight (LMW) PAHs. Winter concentrations of PAHs were higher than those in summer. The transport of PAHs is mainly affected by westerlies, and there are seasonal differences. Source analysis showed that PAHs mainly came from coal and biomass combustion and vehicle emissions, with seasonal differences. This study clarifies the concentration and seasonal variation of PAHs in the northern Tibetan Plateau, which is conducive to understanding the atmospheric transport process and fate of pollutants. The background site of Qilian Mountains located in the Silk Road economic belt has the value and significance of long-term observation of pollutants. [Display omitted]
ISSN:1001-0742
1878-7320
DOI:10.1016/j.jes.2022.02.042