Regulating Spin-State Switching by Integrating Polyoxometalate Anion into Spin Crossover System

Regulating Spin-State Switching by Integrating Polyoxometalate Anion into Spin Crossover System

Polyoxometalate (POM) anions were successfully integrated into Fe­(II) spin crossover (SCO) system, which demonstrates an effective role in regulating spin-state switching properties. Specifically, three drastically different magnetic behaviors of Fe­(II) ion in the identical cation [Fe­(bpp)2]2+ we...

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Veröffentlicht in:Inorganic chemistry 2022-11, Vol.61 (45), p.17932-17936
Hauptverfasser: Li, Jiajia, Sun, Xiao-Peng, Bi, Shiqi, Xu, Minglu, Jia, Siyu, Tang, Zheng, Ma, Pengtao, Wang, Jingping, Tao, Jun, Niu, Jingyang
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Sprache:eng
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Zusammenfassung:Polyoxometalate (POM) anions were successfully integrated into Fe­(II) spin crossover (SCO) system, which demonstrates an effective role in regulating spin-state switching properties. Specifically, three drastically different magnetic behaviors of Fe­(II) ion in the identical cation [Fe­(bpp)2]2+ were achieved by leveraging [Mo6O19]2–, [Mo8O26]4–, and [Na­(Mo8O26)]3–, respectively.
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.2c03032