A cationic fcu -lanthanide MOF enhances the uptake of iodine vapour at room temperature
The first example of a cationic cluster-based fcu –lanthanide metal–organic framework (MOF) bearing an asymmetric linker, herein named UOTT-4, has been designed and fully characterized. Compared to its rare–earth (RE) anionic counterpart (RE-UiO-66), UOTT-4 was found to significantly improve the per...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2022-11, Vol.58 (91), p.12700-12703 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Zwanziger, Clara do Pim, Walace D. Kitos, Alexandros A. Ovens, Jeffrey S. Pallister, Peter J. Murugesu, Muralee |
| description | The first example of a cationic cluster-based
fcu
–lanthanide metal–organic framework (MOF) bearing an asymmetric linker, herein named UOTT-4, has been designed and fully characterized. Compared to its rare–earth (RE) anionic counterpart (RE-UiO-66), UOTT-4 was found to significantly improve the performance towards adsorption of iodine vapour at room temperature, opening avenues for the design of the next-generation cationic porous materials for the beneficial uptake and confinement of target molecules. |
| doi_str_mv | 10.1039/d2cc03299f |
| format | Article |
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| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2022-11, Vol.58 (91), p.12700-12703 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2730319814 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Cations Iodine Metal-organic frameworks Porous materials Room temperature |
| title | A cationic fcu -lanthanide MOF enhances the uptake of iodine vapour at room temperature |
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