A cationic fcu -lanthanide MOF enhances the uptake of iodine vapour at room temperature

A cationic fcu -lanthanide MOF enhances the uptake of iodine vapour at room temperature

The first example of a cationic cluster-based fcu –lanthanide metal–organic framework (MOF) bearing an asymmetric linker, herein named UOTT-4, has been designed and fully characterized. Compared to its rare–earth (RE) anionic counterpart (RE-UiO-66), UOTT-4 was found to significantly improve the per...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2022-11, Vol.58 (91), p.12700-12703
Hauptverfasser: Zwanziger, Clara, do Pim, Walace D., Kitos, Alexandros A., Ovens, Jeffrey S., Pallister, Peter J., Murugesu, Muralee
Format: Artikel
Sprache:eng
Schlagworte:
Cations
Iodine
Metal-organic frameworks
Porous materials
Room temperature
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Zusammenfassung:The first example of a cationic cluster-based fcu –lanthanide metal–organic framework (MOF) bearing an asymmetric linker, herein named UOTT-4, has been designed and fully characterized. Compared to its rare–earth (RE) anionic counterpart (RE-UiO-66), UOTT-4 was found to significantly improve the performance towards adsorption of iodine vapour at room temperature, opening avenues for the design of the next-generation cationic porous materials for the beneficial uptake and confinement of target molecules.
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc03299f