Unveiling selective nitrate reduction to ammonia with Co3O4 nanosheets/TiO2 nanobelt heterostructure catalyst

Co3O4@TiO2/TP acts as an efficient electrocatalyst toward converting NO3– to NH3 at ambient conditions, achieving a high Faradaic efficiency of 93.1% at –0.7 V and a large NH3 yield of up to 875 μmol/h cm−2 at –0.9 V. [Display omitted] Electrochemical nitrate (NO3−) reduction reaction (NO3RR) possesses two-pronged properties for sustainable ammonia (NH3) synthesis and mitigating NO3− contamination in water. However, the sluggish kinetics for the direct eight-electron NO3−-to-NH3 conversion makes a formidable challenge to develop efficient electrocatalysts. Herein, we report a heterostructure of Co3O4 nanosheets decorated TiO2 nanobelt array on titanium plate (Co3O4@TiO2/TP) as an efficient NO3RR electrocatalyst. Both experimental and density theory calculations reveal that the heterostructure of Co3O4@TiO2 establishes a built-in electric field which can optimize the electron migration kinetics, as well as facilitate the adsorption and fixation of NO3− on the electrode surface, ensuring the selectivity to NH3. As expected, the designed Co3O4@TiO2/TP exhibits a remarkable Faradaic efficiency of 93.1 % and a remarkable NH3 yield as high as 875 μmol h−1 cm−2, superior to Co3O4/TP and TiO2/TP. Significantly, it also demonstrates strong electrochemical durability.