Cold plasma-assisted regeneration of biochar for dye adsorption

Environmental remedies, including adsorption-based water purification, are now being asked to meet the requirement for a low-carbon circular economy requiring low energy and low material consumption. In this regard, we tested the possibility of regenerating adsorbents via cold plasma (CP) treatment for less use of adsorbents and no washing solution. In the adsorption of methylene blue (MB) using carbonized rice husk (CRH) and five successive regeneration cycles by CP treatment, the removal efficiencies were maintained at a moderate level (∼70% of the initial performance), unlike five consecutive adsorption without CP treatment (∼9–13% of the initial performance). The regeneration of CRH by CP treatment was also double-checked by the FESEM, EDS, BET, FTIR, XPS, and surface zeta potential measurements. The successfully recovered adsorption capability is related to the remediation of adsorption sites. It is also worth noting that the required power consumption for recycling by CP treatment was about 6.4 times lower than carbonizing new rice husks. This work provides insights into recovering adsorbents using CP without rigorous, costly, and energy-intensive processes. [Display omitted] •Carbonized rice husk (CRH) was used for adsorption-based removal of dye molecules.•The adsorption kinetics was governed by the pseudo-second-order model.•Cold plasma (CP) treatment successfully regenerated the dye-adsorbed CRH.•CP treatment was workable for the five consecutive adsorption tests of the used CRH.•The regeneration mechanism was discussed in detail based on thorough analyses.