Composition control of alloy nanoparticles consisting of bulk-immiscible Au and Rh metals via an ionic liquid/metal sputtering technique for improving their electrocatalytic activity

AuRh bimetallic alloy nanoparticles (NPs) were successfully prepared by simultaneous sputtering of Au and Rh in a room-temperature ionic liquid (RTIL) of N , N -diethyl- N -methyl- N -(2-methoxyethyl) ammonium tetrafluoroborate (DEME-BF 4 ). Bimetallic AuRh alloy NPs of 1–2 nm in size were formed in the RTIL. The alloy composition was controllable by changing the surface areas of Au and Rh plates used as sputtering targets. Loading thus-obtained AuRh NPs on carbon black (CB) powders increased the size of AuRh NPs to ca. 2–8 nm, depending on the Au/Rh ratio. The electrocatalytic activity for oxygen reduction reaction (ORR) of AuRh NP-loaded CB catalysts showed a volcano-type dependence on their composition, in which AuRh NPs with Au surface coverage of 62% exhibited the optimal ORR activity, the specific activity being ca. 5 times higher than that of pure Rh NPs.