Self-Supported 3D-Printed Lattices Containing MXene/Metal–Organic Framework (MXOF) Composite as an Efficient Adsorbent for Wastewater Treatment

Metal–organic frameworks (MOFs) are well-known porous crystalline materials that have been used for the removal of organic pollutants from wastewater. To enhance the adsorption performance of these adsorbents and facilitate their recycling process, we propose a hybrid composite of an MXene/metal–organic framework (MXOF) decorated on a hierarchical and self-supported porous three-dimensional (3D) printed lattice structure (3D-MXOF). In this design, the porous MXOF composite extremely enhanced the specific surface area and synergistically promoted the dye removal efficiency of 3D-printed lattices. Scanning electron microscopy images indicated that the MXOF composite was uniformly decorated on a 3D-printed lattice structure without agglomeration. The resultant supported 3D-MXOF structures were evaluated for the adsorption of anionic dyes. The results revealed high adsorption performance (91.98% for methyl orange and 84.9% for direct red 31 dyes) and fast adsorption kinetics following a pseudo-first-order kinetic model. Moreover, the 3D-MXOF structure possesses a facile recycling process with sustainable adsorption performance after four consecutive adsorption–desorption cycles.