Magnesium ferrite-nitrogen–doped graphene oxide nanocomposite: effective adsorptive removal of lead(II) and arsenic(III)

Magnetic nanocomposites have received immense interest as adsorbents for water decontamination. This paper presents adsorptive properties of nitrogen-doped graphene oxide (N-GO) with magnesium ferrite (MgFe 2 O 4 ) magnetic nanocomposite for removing lead(II) (Pb(II)and arsenite As(III) ions. Transmission electron microscope (TEM) image of synthesized nanocomposite revealed the wrinkled sheets of N-GO containing MgFe 2 O 4 nanoparticles (NPs) with particle size of 5–15 nm distributed over its surface. This nanocomposite displayed higher BET surface area (72.2 m 2 g −1 ) than that of pristine MgFe 2 O 4 NPs (38.4 m 2 g −1 ). Adsorption on the nanocomposite could be described by the Langmuir isotherm with the maximum adsorption capacities were 930 mg/g, and 64.1 mg/g for Pb(II) and As(III), respectively. Whereas, maximum removal efficiencies were observed to be 99.7 ± 0.2% and 93.5 ± 0.1% for Pb(II) and As(III), respectively. The study on the effect of coexisting anions on the adsorption of metal ions showed that the phosphate ions were potential competitors of Pb(II) and As(III) ions to adsorb on the nanocomposite. Significantly, the investigation on adsorption of metal ion in the presence of coexisting heavy metal ions indicated the preferential adsorption of Pb(II) ions as compared to Cd(II), Zn(II) and Ni(II) ions. The effectiveness of the nanocomposite to remove the metal ions in electroplating wastewater was demonstrated.