Soft detoxification of chemical warfare agent simulants and pesticides under pressure
The neutralisation of structurally varied chemical warfare agent simulants (blister and nerve agents) and pesticides (Paraoxon) with the assistance of high pressure is reported. Chloroethyl amines and sulfides (nitrogen and sulfur mustards), phosphonothioates (V-series nerve agents) and phosphates (...
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| Veröffentlicht in: | Organic & biomolecular chemistry 2022-10, Vol.2 (38), p.764-768 |
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| container_title | Organic & biomolecular chemistry |
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| creator | Mansour, Sergui Silva, Valmir B Orth, Elisa S Legros, Julien |
| description | The neutralisation of structurally varied chemical warfare agent simulants (blister and nerve agents) and pesticides (Paraoxon) with the assistance of high pressure is reported. Chloroethyl amines and sulfides (nitrogen and sulfur mustards), phosphonothioates (V-series nerve agents) and phosphates (pesticide) readily react with simple nucleophilic scavengers (alcohols, amines) at
P
> 14 000 bar.
The combination of very high pressure and simple nucleophilic scavengers (alcohols, amines) promotes the detoxification of nitrogen and sulfur mustards, V-series nerve agents and pesticides. |
| doi_str_mv | 10.1039/d2ob01217k |
| format | Article |
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P
> 14 000 bar.
The combination of very high pressure and simple nucleophilic scavengers (alcohols, amines) promotes the detoxification of nitrogen and sulfur mustards, V-series nerve agents and pesticides.</description><identifier>ISSN: 1477-0520</identifier><identifier>EISSN: 1477-0539</identifier><identifier>DOI: 10.1039/d2ob01217k</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Alcohols ; Amines ; Blistering ; Chemical Sciences ; Chemical warfare ; Detoxification ; High pressure ; Nerve agents ; Nerves ; Paraoxon ; Pesticides ; Phosphates ; Sulfur</subject><ispartof>Organic & biomolecular chemistry, 2022-10, Vol.2 (38), p.764-768</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c384t-a550e79d61cebf877d762a54cd7c9e619b19d73ecc7ffda003a9990043b85a9d3</citedby><cites>FETCH-LOGICAL-c384t-a550e79d61cebf877d762a54cd7c9e619b19d73ecc7ffda003a9990043b85a9d3</cites><orcidid>0000-0002-4807-7897 ; 0000-0001-6874-3650 ; 0000-0001-6686-7721</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27923,27924</link.rule.ids><backlink>$$Uhttps://hal.science/hal-03838940$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Mansour, Sergui</creatorcontrib><creatorcontrib>Silva, Valmir B</creatorcontrib><creatorcontrib>Orth, Elisa S</creatorcontrib><creatorcontrib>Legros, Julien</creatorcontrib><title>Soft detoxification of chemical warfare agent simulants and pesticides under pressure</title><title>Organic & biomolecular chemistry</title><description>The neutralisation of structurally varied chemical warfare agent simulants (blister and nerve agents) and pesticides (Paraoxon) with the assistance of high pressure is reported. Chloroethyl amines and sulfides (nitrogen and sulfur mustards), phosphonothioates (V-series nerve agents) and phosphates (pesticide) readily react with simple nucleophilic scavengers (alcohols, amines) at
P
> 14 000 bar.
The combination of very high pressure and simple nucleophilic scavengers (alcohols, amines) promotes the detoxification of nitrogen and sulfur mustards, V-series nerve agents and pesticides.</description><subject>Alcohols</subject><subject>Amines</subject><subject>Blistering</subject><subject>Chemical Sciences</subject><subject>Chemical warfare</subject><subject>Detoxification</subject><subject>High pressure</subject><subject>Nerve agents</subject><subject>Nerves</subject><subject>Paraoxon</subject><subject>Pesticides</subject><subject>Phosphates</subject><subject>Sulfur</subject><issn>1477-0520</issn><issn>1477-0539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpd0c9LwzAUB_AiCs7pxbsQ8KJCNWnapjnO-WPiYAfduaTJi8vsmpq0_vjvzZxM8JSXx4fHe3yj6JjgS4Ipv1KJrTBJCHvdiQYkZSzGGeW72zrB-9GB90uMCWd5OojmT1Z3SEFnP402UnTGNshqJBewCt8afQinhQMkXqDpkDervhZN55FoFGrBd0YaBR71jQKHWgfe9w4Ooz0tag9Hv-8wmt_dPo8n8XR2_zAeTWNJi7SLRZZhYFzlREKlC8YUyxORpVIxySEnvCJcMQpSMq2VwJgKzjnGKa2KTHBFh9H5Zu5C1GXrzEq4r9IKU05G03Ldw7SgBU_xOwn2bGNbZ9_6sHm5Ml5CHc4B2_syYYTlgbIi0NN_dGl714RLgkoIYZhkSVAXGyWd9d6B3m5AcLlOo7xJZtc_aTwGfLLBzsut-0uLfgO39oYx</recordid><startdate>20221005</startdate><enddate>20221005</enddate><creator>Mansour, Sergui</creator><creator>Silva, Valmir B</creator><creator>Orth, Elisa S</creator><creator>Legros, Julien</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QO</scope><scope>7T7</scope><scope>7TM</scope><scope>8FD</scope><scope>C1K</scope><scope>FR3</scope><scope>P64</scope><scope>7X8</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-4807-7897</orcidid><orcidid>https://orcid.org/0000-0001-6874-3650</orcidid><orcidid>https://orcid.org/0000-0001-6686-7721</orcidid></search><sort><creationdate>20221005</creationdate><title>Soft detoxification of chemical warfare agent simulants and pesticides under pressure</title><author>Mansour, Sergui ; Silva, Valmir B ; Orth, Elisa S ; Legros, Julien</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c384t-a550e79d61cebf877d762a54cd7c9e619b19d73ecc7ffda003a9990043b85a9d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Alcohols</topic><topic>Amines</topic><topic>Blistering</topic><topic>Chemical Sciences</topic><topic>Chemical warfare</topic><topic>Detoxification</topic><topic>High pressure</topic><topic>Nerve agents</topic><topic>Nerves</topic><topic>Paraoxon</topic><topic>Pesticides</topic><topic>Phosphates</topic><topic>Sulfur</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mansour, Sergui</creatorcontrib><creatorcontrib>Silva, Valmir B</creatorcontrib><creatorcontrib>Orth, Elisa S</creatorcontrib><creatorcontrib>Legros, Julien</creatorcontrib><collection>CrossRef</collection><collection>Biotechnology Research Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Nucleic Acids Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Engineering Research Database</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Organic & biomolecular chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mansour, Sergui</au><au>Silva, Valmir B</au><au>Orth, Elisa S</au><au>Legros, Julien</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Soft detoxification of chemical warfare agent simulants and pesticides under pressure</atitle><jtitle>Organic & biomolecular chemistry</jtitle><date>2022-10-05</date><risdate>2022</risdate><volume>2</volume><issue>38</issue><spage>764</spage><epage>768</epage><pages>764-768</pages><issn>1477-0520</issn><eissn>1477-0539</eissn><abstract>The neutralisation of structurally varied chemical warfare agent simulants (blister and nerve agents) and pesticides (Paraoxon) with the assistance of high pressure is reported. Chloroethyl amines and sulfides (nitrogen and sulfur mustards), phosphonothioates (V-series nerve agents) and phosphates (pesticide) readily react with simple nucleophilic scavengers (alcohols, amines) at
P
> 14 000 bar.
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| fulltext | fulltext |
| identifier | ISSN: 1477-0520 |
| ispartof | Organic & biomolecular chemistry, 2022-10, Vol.2 (38), p.764-768 |
| issn | 1477-0520 1477-0539 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_2717694078 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Alcohols Amines Blistering Chemical Sciences Chemical warfare Detoxification High pressure Nerve agents Nerves Paraoxon Pesticides Phosphates Sulfur |
| title | Soft detoxification of chemical warfare agent simulants and pesticides under pressure |
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