Effect of tartrate content on aging and deposition condition of copper–tin electrodeposits from a non-cyanide acid bath

The effect of the presence of tartrate additive on the chemical stability of a Cu–Sn acid bath was evaluated. It was observed that this additive hinders decomposition of the Cu/Sn deposition bath with storage time, since the decrease in electrochemical efficiency was attenuated. In addition, it was...

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Veröffentlicht in:Surface & coatings technology 2002-08, Vol.157 (1), p.14-18
Hauptverfasser: Carlos, I.A, Bidoia, E.D, Pallone, E.M.J.A, Almeida, M.R.H, Souza, C.A.C
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container_end_page 18
container_issue 1
container_start_page 14
container_title Surface & coatings technology
container_volume 157
creator Carlos, I.A
Bidoia, E.D
Pallone, E.M.J.A
Almeida, M.R.H
Souza, C.A.C
description The effect of the presence of tartrate additive on the chemical stability of a Cu–Sn acid bath was evaluated. It was observed that this additive hinders decomposition of the Cu/Sn deposition bath with storage time, since the decrease in electrochemical efficiency was attenuated. In addition, it was observed that optimal galvanostatic deposition with or without tartrate occurs at approximately 11 mA cm −2. However, in the presence of tartrate the deposition charge was lower, leading to lower energy consumption. SEM analysis showed that the tartrate added to the plating bath caused a marked change in the morphology of the Cu/Sn films obtained galvanostatically.
doi_str_mv 10.1016/S0257-8972(02)00139-1
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source Elsevier ScienceDirect Journals Complete
subjects Applied sciences
Copper–tin alloy
Cross-disciplinary physics: materials science
rheology
Electrodeposition, electroplating
Electroplating
Exact sciences and technology
Materials science
Metals. Metallurgy
Methods of deposition of films and coatings
film growth and epitaxy
Physics
Tartrate
title Effect of tartrate content on aging and deposition condition of copper–tin electrodeposits from a non-cyanide acid bath
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