Reactive Azeotropes in Kinetically Controlled Reactive Distillation

Reactive Azeotropes in Kinetically Controlled Reactive Distillation

In this paper, a novel method for the determination of reactive azeotropes is presented that applies to chemical reactions that do not reach chemical equilibrium. The principles of the methodology are explained for ideal mixtures. For the MTBE- and TAME-synthesis the results obtained with this metho...

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Veröffentlicht in:Chemical engineering research & design 1999-10, Vol.77 (7), p.613-618
Hauptverfasser: Frey, Th, Stichlmair, J.
Format: Artikel
Sprache:eng
Schlagworte:
Applied sciences
Chemical engineering
Distillation
Exact sciences and technology
MTBE
reactive azeotropes
reactive distillation
TAME
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Beschreibung
Zusammenfassung:In this paper, a novel method for the determination of reactive azeotropes is presented that applies to chemical reactions that do not reach chemical equilibrium. The principles of the methodology are explained for ideal mixtures. For the MTBE- and TAME-synthesis the results obtained with this methodology are compared to the results from Thiel et al.
ISSN:0263-8762
DOI:10.1205/026387699526656