Regulation of coordination and doping environment via target molecular transformation for boosting selective photocatalytic ability
Here, a novel transformed CdO with low coordination and N doping environment was simply synthesized through the involvement of the target molecule tetracycline (TC). The results showed that the shedding of surface hydroxyl groups led to a low coordination environment, and N doping formed a new dopin...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2022-09, Vol.58 (72), p.10036-10039 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Zhou, Guosheng Cheng, Yu Yu, Zehui Liu, Xinlin Chen, Dehai Wang, Jiaqi Hang, Ying Xu, Yangrui Li, Chunxiang Lu, Ziyang |
| description | Here, a novel transformed CdO with low coordination and N doping environment was simply synthesized through the involvement of the target molecule tetracycline (TC). The results showed that the shedding of surface hydroxyl groups led to a low coordination environment, and N doping formed a new doping energy level, which increased the charge density and promoted the migration and separation of photo-generated carriers. Its photocatalytic performance was 4.32 times higher than that of hydroxy-rich CdO and the selectivity coefficient was 4.8. Combined with theoretical calculation and
in situ
Attenuated Total Reflectance Fourier Transform Infrared (ATR-FTIR) analysis, the significant improvement of selectivity was due to the interaction of the doped N atom with the methyl carbon in TC. This work provided a new idea for the simultaneous construction of low coordination environment and N-doped materials for efficient selective photocatalysis. |
| doi_str_mv | 10.1039/d2cc03373a |
| format | Article |
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in situ
Attenuated Total Reflectance Fourier Transform Infrared (ATR-FTIR) analysis, the significant improvement of selectivity was due to the interaction of the doped N atom with the methyl carbon in TC. This work provided a new idea for the simultaneous construction of low coordination environment and N-doped materials for efficient selective photocatalysis.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d2cc03373a</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Charge density ; Coordination ; Doping ; Energy levels ; Fourier transforms ; Hydroxyl groups ; Infrared analysis ; Photocatalysis ; Selectivity</subject><ispartof>Chemical communications (Cambridge, England), 2022-09, Vol.58 (72), p.10036-10039</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c292t-f90908615139807ff45402c8c4ece0b935cc90b1ca46fc4f37e7fa8ad17fefef3</citedby><cites>FETCH-LOGICAL-c292t-f90908615139807ff45402c8c4ece0b935cc90b1ca46fc4f37e7fa8ad17fefef3</cites><orcidid>0000-0003-3775-4167 ; 0000-0001-8873-3695</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Zhou, Guosheng</creatorcontrib><creatorcontrib>Cheng, Yu</creatorcontrib><creatorcontrib>Yu, Zehui</creatorcontrib><creatorcontrib>Liu, Xinlin</creatorcontrib><creatorcontrib>Chen, Dehai</creatorcontrib><creatorcontrib>Wang, Jiaqi</creatorcontrib><creatorcontrib>Hang, Ying</creatorcontrib><creatorcontrib>Xu, Yangrui</creatorcontrib><creatorcontrib>Li, Chunxiang</creatorcontrib><creatorcontrib>Lu, Ziyang</creatorcontrib><title>Regulation of coordination and doping environment via target molecular transformation for boosting selective photocatalytic ability</title><title>Chemical communications (Cambridge, England)</title><description>Here, a novel transformed CdO with low coordination and N doping environment was simply synthesized through the involvement of the target molecule tetracycline (TC). The results showed that the shedding of surface hydroxyl groups led to a low coordination environment, and N doping formed a new doping energy level, which increased the charge density and promoted the migration and separation of photo-generated carriers. Its photocatalytic performance was 4.32 times higher than that of hydroxy-rich CdO and the selectivity coefficient was 4.8. Combined with theoretical calculation and
in situ
Attenuated Total Reflectance Fourier Transform Infrared (ATR-FTIR) analysis, the significant improvement of selectivity was due to the interaction of the doped N atom with the methyl carbon in TC. This work provided a new idea for the simultaneous construction of low coordination environment and N-doped materials for efficient selective photocatalysis.</description><subject>Charge density</subject><subject>Coordination</subject><subject>Doping</subject><subject>Energy levels</subject><subject>Fourier transforms</subject><subject>Hydroxyl groups</subject><subject>Infrared analysis</subject><subject>Photocatalysis</subject><subject>Selectivity</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpdkU1LxDAQhoMouK5e_AUBLyJU87lpj1I_YUEQBW8lTZM1S5vUJLuwZ_-4WevJmcO8A887DLwAnGN0jRGtbjqiFKJUUHkAZpguWMFZ-XG417wqBGX8GJzEuEa5MC9n4PtVrza9TNY76A1U3ofOummXroOdH61bQe22Nng3aJfg1kqYZFjpBAffa5XtAaYgXTQ-DJM1K9h6H9PeHHWmkt1qOH765JVMst8lq6BsbW_T7hQcGdlHffY35-D94f6tfiqWL4_P9e2yUKQiqTAVqlC5wBzTqkTCGMYZIqpUTCuN2opypSrUYiXZwihmqNDCyFJ2WBidm87B5XR3DP5ro2NqBhuV7nvptN_EhgjESoG4QBm9-Ieu_Sa4_F2mMCaMcC4ydTVRKvgYgzbNGOwgw67BqNnn0dyRuv7N45b-AKILgXY</recordid><startdate>20220908</startdate><enddate>20220908</enddate><creator>Zhou, Guosheng</creator><creator>Cheng, Yu</creator><creator>Yu, Zehui</creator><creator>Liu, Xinlin</creator><creator>Chen, Dehai</creator><creator>Wang, Jiaqi</creator><creator>Hang, Ying</creator><creator>Xu, Yangrui</creator><creator>Li, Chunxiang</creator><creator>Lu, Ziyang</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-3775-4167</orcidid><orcidid>https://orcid.org/0000-0001-8873-3695</orcidid></search><sort><creationdate>20220908</creationdate><title>Regulation of coordination and doping environment via target molecular transformation for boosting selective photocatalytic ability</title><author>Zhou, Guosheng ; Cheng, Yu ; Yu, Zehui ; Liu, Xinlin ; Chen, Dehai ; Wang, Jiaqi ; Hang, Ying ; Xu, Yangrui ; Li, Chunxiang ; Lu, Ziyang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c292t-f90908615139807ff45402c8c4ece0b935cc90b1ca46fc4f37e7fa8ad17fefef3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Charge density</topic><topic>Coordination</topic><topic>Doping</topic><topic>Energy levels</topic><topic>Fourier transforms</topic><topic>Hydroxyl groups</topic><topic>Infrared analysis</topic><topic>Photocatalysis</topic><topic>Selectivity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhou, Guosheng</creatorcontrib><creatorcontrib>Cheng, Yu</creatorcontrib><creatorcontrib>Yu, Zehui</creatorcontrib><creatorcontrib>Liu, Xinlin</creatorcontrib><creatorcontrib>Chen, Dehai</creatorcontrib><creatorcontrib>Wang, Jiaqi</creatorcontrib><creatorcontrib>Hang, Ying</creatorcontrib><creatorcontrib>Xu, Yangrui</creatorcontrib><creatorcontrib>Li, Chunxiang</creatorcontrib><creatorcontrib>Lu, Ziyang</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhou, Guosheng</au><au>Cheng, Yu</au><au>Yu, Zehui</au><au>Liu, Xinlin</au><au>Chen, Dehai</au><au>Wang, Jiaqi</au><au>Hang, Ying</au><au>Xu, Yangrui</au><au>Li, Chunxiang</au><au>Lu, Ziyang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Regulation of coordination and doping environment via target molecular transformation for boosting selective photocatalytic ability</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2022-09-08</date><risdate>2022</risdate><volume>58</volume><issue>72</issue><spage>10036</spage><epage>10039</epage><pages>10036-10039</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>Here, a novel transformed CdO with low coordination and N doping environment was simply synthesized through the involvement of the target molecule tetracycline (TC). The results showed that the shedding of surface hydroxyl groups led to a low coordination environment, and N doping formed a new doping energy level, which increased the charge density and promoted the migration and separation of photo-generated carriers. Its photocatalytic performance was 4.32 times higher than that of hydroxy-rich CdO and the selectivity coefficient was 4.8. Combined with theoretical calculation and
in situ
Attenuated Total Reflectance Fourier Transform Infrared (ATR-FTIR) analysis, the significant improvement of selectivity was due to the interaction of the doped N atom with the methyl carbon in TC. This work provided a new idea for the simultaneous construction of low coordination environment and N-doped materials for efficient selective photocatalysis.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d2cc03373a</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0003-3775-4167</orcidid><orcidid>https://orcid.org/0000-0001-8873-3695</orcidid></addata></record> |
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| ispartof | Chemical communications (Cambridge, England), 2022-09, Vol.58 (72), p.10036-10039 |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Charge density Coordination Doping Energy levels Fourier transforms Hydroxyl groups Infrared analysis Photocatalysis Selectivity |
| title | Regulation of coordination and doping environment via target molecular transformation for boosting selective photocatalytic ability |
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