The structure of Na2O-Al2O3-SiO2 glass: impact on sodium ion exchange in H2O and D2O

The kinetics of matrix dissolution and alkali-exchange for a series of sodium aluminosilicate glass compositions was determined at constant temperature and solution pH(D) under conditions of SiO2 saturation. Steady state release rate for Na was 10-50 times faster than the rate of matrix dissolution, demonstrating that alkali exchange is an important long-term reaction mechanism that must be considered when modeling systems near saturation with respect to dissolved glass components. Na release rates were 30% slower in D2O compared to rates in H2O, but matrix dissolution rates were unaffected. These results are consistent with rupture of the OH bond as the rate-limiting reaction in Na+-H+ exchange whereas matrix dissolution is controlled by OH- or H2O catalyzed hydrolysis of SiOSi and SiOAl bonds. Changes in Na exchange rate with increasing Al2O3 content could not be reconciled with changes in the number of non-bridging O (NBO) sites in the glass alone. A simple model was used to estimate a structural energy barrier for alkali ion exchange using NaO bond length and co-ordination as measured by Na K-edge X-ray absorption spectroscopy, and binding energy shifts for SiONa sites measured by XPS. The energy barrier was calculated to increase from 34 kJ mol-1 for Na2O*2SiO2 glass to 49 kJ mol-1 for a glass containing 15 mol% Al2O3, consistent with stronger bonding of Na on NBO sites and increasing mechanical stiffness of the glass network with increasing Al content. The calculated ion-exchange enthalpies were then used to calculate Na ion-exchange rates as a function of glass composition. Agreement between the calculated and measured Na ion exchange rates was excellent. 56 refs.