Dual chirped-pulse electro-optical frequency comb method for simultaneous molecular spectroscopy and dynamics studies: formic acid in the terahertz region

An electro-optic dual-comb system based on chirped-pulse waveforms is used to simultaneously acquire temporally magnified rapid passage signals and normal spectral line shapes from the back-transformation to the time domain. Multi-heterodyne terahertz (THz) wave generation and detection is performed with the difference frequency mixing of two free-running lasers. The method is used to obtain THz spectra of formic acid in the 10 cm -1 to 20 cm -1 (300 GHz–600 GHz) region over a range of pressures. The method is widely applicable across other spectral regions for investigations of the transient dynamics and spectroscopy of molecular systems.