Anionic or neutral? the charge of Ni8 cubes in metal–organic framework compounds

Anionic or neutral? the charge of Ni8 cubes in metal–organic framework compounds

The cubic SBU Ni8X6L6 (X = OH−/H2O, L = ligand) is of great interest due to its stability and potential applications when integrated in MOFs. Here, we investigate by detailed DRIFTS measurements and exchange reactions whether it is found to be neutral in MOFs, as previously assumed in the literature...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2022-08, Vol.58 (67), p.9349-9352
Hauptverfasser: Freund, Ralph, Kalytta-Mewes, Andreas, Kraft, Maryana, Volkmer, Dirk
Format: Artikel
Sprache:eng
Schlagworte:
Cubes
Metal-organic frameworks
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Zusammenfassung:The cubic SBU Ni8X6L6 (X = OH−/H2O, L = ligand) is of great interest due to its stability and potential applications when integrated in MOFs. Here, we investigate by detailed DRIFTS measurements and exchange reactions whether it is found to be neutral in MOFs, as previously assumed in the literature, or whether it can show anionic character, as observed in complexes.
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc03016k