Mechanofluorochromism of 2‐Biarylyl Cinchoninic Acids with High Sensitivity and Large Mechanochromic Shift

In recent years, organic mechanofluorochromism (MFC) materials have attracted wide attention in many fields. However, the exploration of MFC materials with high‐contrast, high‐sensitivity and high‐responsiveness remains a challenge. Herein, a series of MFC materials with 2‐biarylyl cinchoninic acid skeleton were successfully established, which are based on interconversion of classical/frustrated Brønsted pairs. These compounds have the mechanochromic shift of up to 115 nm, as well as the property of stunning sensitivity and multiple responses to external mechanical force stimuli. The luminescence properties can be easily tuned by changing the substituents. A series of MFC materials with a 2‐biarylyl cinchoninic acid skeleton have been synthesized, which are based on interconversion of classical/ frustrated Brønsted pairs. These materials have mechanochromic shift of up to 115 nm, as well as highly contrast, highly sensitivity and highly responsiveness properties.