NASIGLAS structure and properties
ZrO 2-deficient compositions of NASICON (Na 1+ x Zr 2− x/3 Si x P 3− x O 12−2 x/3 where 0⩽ x⩽3) have been prepared in glassy form (sodium superionic conducting glass (NASIGLAS)) using the melt quench method. The corresponding glass-ceramics have also been produced by heat treatment at appropriate te...
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| Veröffentlicht in: | Journal of non-crystalline solids 2001-11, Vol.293, p.709-714 |
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| container_title | Journal of non-crystalline solids |
| container_volume | 293 |
| creator | Niyompan, A. Holland, D. |
| description | ZrO
2-deficient compositions of NASICON (Na
1+
x
Zr
2−
x/3
Si
x
P
3−
x
O
12−2
x/3
where 0⩽
x⩽3) have been prepared in glassy form (sodium superionic conducting glass (NASIGLAS)) using the melt quench method. The corresponding glass-ceramics have also been produced by heat treatment at appropriate temperatures identified from DTA. From
29
Si
MAS
NMR
, it is found that [SiO
4] tetrahedra are predominantly Q
2 species for composition
x=3.0, but are mixed Q
2–Q
3 for
x |
| doi_str_mv | 10.1016/S0022-3093(01)00781-5 |
| format | Article |
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2-deficient compositions of NASICON (Na
1+
x
Zr
2−
x/3
Si
x
P
3−
x
O
12−2
x/3
where 0⩽
x⩽3) have been prepared in glassy form (sodium superionic conducting glass (NASIGLAS)) using the melt quench method. The corresponding glass-ceramics have also been produced by heat treatment at appropriate temperatures identified from DTA. From
29
Si
MAS
NMR
, it is found that [SiO
4] tetrahedra are predominantly Q
2 species for composition
x=3.0, but are mixed Q
2–Q
3 for
x<3. Crystalline Na
2ZrSi
2O
7 is found in all the corresponding glass-ceramic samples. The complex plane impedance method was used to determine the conductivity of NASIGLAS, which appears to be a complex function of mobility and concentration of Na
+.
23
Na
NMR
indicates anomalous motion when
x=2.5. Low solubility of ZrO
2 is noticeable in glasses with low value of
x.</description><identifier>ISSN: 0022-3093</identifier><identifier>EISSN: 1873-4812</identifier><identifier>DOI: 10.1016/S0022-3093(01)00781-5</identifier><language>eng</language><publisher>Elsevier B.V</publisher><ispartof>Journal of non-crystalline solids, 2001-11, Vol.293, p.709-714</ispartof><rights>2001 Elsevier Science B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c371t-65fa5fc283aede534ef3b853574d7f3cb85fafd7854ee6309ddfe439d190c3e3</citedby><cites>FETCH-LOGICAL-c371t-65fa5fc283aede534ef3b853574d7f3cb85fafd7854ee6309ddfe439d190c3e3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/S0022-3093(01)00781-5$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Niyompan, A.</creatorcontrib><creatorcontrib>Holland, D.</creatorcontrib><title>NASIGLAS structure and properties</title><title>Journal of non-crystalline solids</title><description>ZrO
2-deficient compositions of NASICON (Na
1+
x
Zr
2−
x/3
Si
x
P
3−
x
O
12−2
x/3
where 0⩽
x⩽3) have been prepared in glassy form (sodium superionic conducting glass (NASIGLAS)) using the melt quench method. The corresponding glass-ceramics have also been produced by heat treatment at appropriate temperatures identified from DTA. From
29
Si
MAS
NMR
, it is found that [SiO
4] tetrahedra are predominantly Q
2 species for composition
x=3.0, but are mixed Q
2–Q
3 for
x<3. Crystalline Na
2ZrSi
2O
7 is found in all the corresponding glass-ceramic samples. The complex plane impedance method was used to determine the conductivity of NASIGLAS, which appears to be a complex function of mobility and concentration of Na
+.
23
Na
NMR
indicates anomalous motion when
x=2.5. Low solubility of ZrO
2 is noticeable in glasses with low value of
x.</description><issn>0022-3093</issn><issn>1873-4812</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2001</creationdate><recordtype>article</recordtype><recordid>eNqNkEFLxDAQhYMouK7-BGG9iB6qSadp0pOURdeFoofuPcRkApHutiat4L-33RWvOpeZw3tvZj5CLhm9Y5Tl9zWlaZoALeCGsltKhWQJPyIzJgUkmWTpMZn9Sk7JWYzvdCwBckauXsp6varKehH7MJh-CLjQO7voQtth6D3Gc3LidBPx4qfPyebpcbN8TqrX1XpZVokBwfok505zZ1IJGi1yyNDBm-TARWaFAzPOTjsrJM8Q8_ESax1mUFhWUAMIc3J9iB03fwwYe7X10WDT6B22Q1RpLrOCF_xfwlzkk5AfhCa0MQZ0qgt-q8OXYlRN4NQenJqoKMrUHpyafA8HH47ffnoMKhqPO4PWBzS9sq3_I-EbkTVzqQ</recordid><startdate>20011101</startdate><enddate>20011101</enddate><creator>Niyompan, A.</creator><creator>Holland, D.</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><scope>7QQ</scope></search><sort><creationdate>20011101</creationdate><title>NASIGLAS structure and properties</title><author>Niyompan, A. ; Holland, D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c371t-65fa5fc283aede534ef3b853574d7f3cb85fafd7854ee6309ddfe439d190c3e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2001</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Niyompan, A.</creatorcontrib><creatorcontrib>Holland, D.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Ceramic Abstracts</collection><jtitle>Journal of non-crystalline solids</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Niyompan, A.</au><au>Holland, D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>NASIGLAS structure and properties</atitle><jtitle>Journal of non-crystalline solids</jtitle><date>2001-11-01</date><risdate>2001</risdate><volume>293</volume><spage>709</spage><epage>714</epage><pages>709-714</pages><issn>0022-3093</issn><eissn>1873-4812</eissn><abstract>ZrO
2-deficient compositions of NASICON (Na
1+
x
Zr
2−
x/3
Si
x
P
3−
x
O
12−2
x/3
where 0⩽
x⩽3) have been prepared in glassy form (sodium superionic conducting glass (NASIGLAS)) using the melt quench method. The corresponding glass-ceramics have also been produced by heat treatment at appropriate temperatures identified from DTA. From
29
Si
MAS
NMR
, it is found that [SiO
4] tetrahedra are predominantly Q
2 species for composition
x=3.0, but are mixed Q
2–Q
3 for
x<3. Crystalline Na
2ZrSi
2O
7 is found in all the corresponding glass-ceramic samples. The complex plane impedance method was used to determine the conductivity of NASIGLAS, which appears to be a complex function of mobility and concentration of Na
+.
23
Na
NMR
indicates anomalous motion when
x=2.5. Low solubility of ZrO
2 is noticeable in glasses with low value of
x.</abstract><pub>Elsevier B.V</pub><doi>10.1016/S0022-3093(01)00781-5</doi><tpages>6</tpages></addata></record> |
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| issn | 0022-3093 1873-4812 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_26849595 |
| source | Access via ScienceDirect (Elsevier) |
| title | NASIGLAS structure and properties |
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