New insights into the interaction of triethylphosphine oxide with silica surface: exchange between different surface species

Although chemical shift values of triethylphosphine oxide (TEPO) adsorbed on acidic solids have been considered as an indication of acid strength, in this work we demonstrate that the chemical shift depends also on the adsorbed amount of TEPO. On silica, the presence of three different adsorbed species, physisorbed on non-acidic surface, chemisorbed through a single H bond and chemisorbed through two H bonds, can be detected by the correlation of the 31 P chemical shift with the TEPO adsorbed amount. TEPO chemical exchange between the different sites is demonstrated by the single NMR signal obtained in all the cases, and also by the variation of the line width, which is broader at low surface coverage due to the slower chemical exchange because of the longer average distance between surface sites. TEPO adsorbed on silica shows a single signal, due to mobility, and three types of adsorption modes, physisorption, chemisorption through one H-bond and through two H-bonds, as demonstrated by 31 P solid state NMR at different surface coverage.