Developments in Surface/Interface Engineering of Ni‐Rich Layered Cathode Materials

Ni‐rich layered cathodes with high energy densities reveal an enormous potential for lithium‐ion batteries (LIBs), however, their poor stability and reliability have inhibited their application. To ensure their stability over extensive cycles at high voltage, surface/interface modifications are necessary to minimize the adverse reactions at the cathode‐electrolyte interface (CEI), which is a critical factor impeding electrode performance. Therefore, this review provides a comprehensive discussion on the surface engineering of Ni‐rich cathode materials for enhancing their lithium storage property. Based on the structural characteristics of the Ni‐rich cathode, the major failure mechanisms of these structures during synthesis and operation are summarized. Then the existing surface modification techniques are discussed and compared. Recent breakthroughs in various surface coatings and modification strategies are categorized and their unique functionalities in structural protection and performance‐enhancing are elaborated. Finally, the challenges and outlook on the Ni‐rich cathode materials are also proposed. Surface/interface modifications are an effective strategy to ensure the stability of Ni‐rich layered cathodes with high energy densities for lithium‐ion batteries (LIBs). This review summarized the major failure mechanisms of the Ni‐rich cathode, discussed the existing surface modification techniques, categorized the recent breakthroughs in various surface coatings and modification strategies, and elaborated their unique functionalities in structural protection and performance‐enhancing. Furthermore, we also proposed the challenges and outlook on the Ni‐rich cathode materials.