A novel nanocomposite (g-C3N4/Fe3O4@P2W15V3) with dual function in organic dyes degradation and cysteine sensing

Among the important needs of human societies is the elimination of environmental pollution and also the construction of high-performance and inexpensive biosensors. In this regard, the construction of multi-functional composites has been considered. A novel magnetic graphite carbon nitride decorated...

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Veröffentlicht in:Chemosphere (Oxford) 2022-10, Vol.304, p.135305-135305, Article 135305
Hauptverfasser: Housaindokht, Mohammad Reza, Jamshidi, Ali, Zonoz, Farrokhzad Mohammadi, Firouzi, Mojtaba
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Sprache:eng
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Zusammenfassung:Among the important needs of human societies is the elimination of environmental pollution and also the construction of high-performance and inexpensive biosensors. In this regard, the construction of multi-functional composites has been considered. A novel magnetic graphite carbon nitride decorated by tri-vanadium substituted Dawson-type heteropolytungstate nanocomposite (C3N4/Fe3O4@P2W15V3) effectively synthesized and characterized by prevalent functional analysis. The prepared nano-catalyst presents bi-functional usage involving photocatalytic removal of dyes (methylene blue, congo red and phenyl red) (around 98%) under visible light radiation and greatly sensitive colorimetric sensing of cysteine in an aqueous media. Moreover, synthesized nano-catalyst successfully recovered five times without any considerable deficiency on its photocatalytic ability. Further, Moreover, we propose a novel method for cysteine detection based on the C3N4/Fe3O4@P2W15V3 nanocomposite. This nanocomposite displayed a privileged catalytic feature for cysteine oxidation to extend a clock reaction of methylene blue as an indicator in the presence of NaBH4 in acidic solution. More importantly, this colorimetric sensing method of cysteine presents an easy, low-cost, selective, and rapid colorimetric assay with a detection limit value of 7.2 μM in the acceptable linear range of 5–600 μM. [Display omitted] •The Preparation and characterization of a novel and green photocatalyst abbreviated g-C3N4/Fe3O4@P2W15V3.•The g-C3N4/Fe3O4@P2W15V3 has been used for the degradation of organic dyes.•The g-C3N4/Fe3O4@P2W15V3 photocatalyst exhibits great recovery ability and photodegradation activity than pristine g-C3N4.•Efficient colorimetric sensing of Cys with g-C3N4/Fe3O4@P2W15V3 system.
ISSN:0045-6535
1879-1298
DOI:10.1016/j.chemosphere.2022.135305