Janus bimetallic materials as efficient electrocatalysts for hydrogen oxidation and evolution reactions

Benefiting from Ni can provide excellent hydrogen adsorption free energy and tungsten has ideal hydroxide adsorption free energy, the designed Janus Ni/W bimetallic materials can provide remarkable HER/HOR activity. [Display omitted] The development of hydrogen energy is limited by the high cost of platinum group metals (PGM). There is an urgent need to design efficient PGM-free electrocatalysts in the hydrogen electrode. Herein, Janus Ni/W bimetallic materials are proposed as an effective PGM-free bifunctional hydrogen electrocatalyst. By constructing the bimetallic materials, a synergistic effect is realized to enhance the reaction kinetics and improve the catalytic performance. In general, Ni can provide excellent Had sites, and W serves as OHad sites. Therefore, the synergistic effect of Ni and W can improve the kinetics of hydrogen evolution reaction and the hydroxide oxidation reaction. Ni/W@NF can obtain the hydrogen evolution reaction current density of 10 mA cm−2 with an overpotential of only 62.6 mV, and the exchange current density of hydroxide oxidation reaction can reach 1.83 mA cm−2. This work provides a new idea for the design of high-efficiency and low-cost PGM-free bifunctional hydrogen electrocatalysts.