Solid Oxide Fuel Cell with Composite Electrolyte Consisting of Samaria‐Doped Ceria and Yttria‐Stabilized Zirconia

A composite oxide containing samaria-doped ceria (SDC), and yttria-stabilised zirconia (YSZ), was developed as an electrolyte for a solid oxide fuel cell (SOFC). A SOFC with a YSZ electrolyte was characterised by a high open-circuit voltage (OCV) and a steep decrease in voltage with increasing current, whereas that with a SDC electrolyte exhibited a low OCV and a gradual decrease of its V-I curve. A biphasic electrolyte microstructure was proposed in which SDC grains are dispersed in a YSZ matrix. In this composite structure, the electronic conduction caused by reduction of the SDC was effectively blocked by the YSZ matrix. An SOFC with this composite electrolyte offered the advantages of high OCV and gradual decrease of the V-I curve. The SDC content and the particle size significantly affected the power-generation characteristics of a cell with this composite electrolyte. The electrode polarisation was significantly lowered by using the SDC or the composite electrolyte. 19 refs.