An air-stable, well-defined palladium-BIAN-NHC chloro dimer: a fast-activating, highly efficient catalyst for cross-coupling

We report the synthesis, characterization and reactivity of an air-stable, well-defined acenaphthoimidazolylidene palladium-BIAN-NHC chloro dimer complex, [Pd(BIAN-IPr)(μ-Cl)Cl] 2 . This rapidly activating catalyst merges the reactive properties of palladium chloro dimers, [Pd(NHC)(μ-Cl)Cl] 2 , with the attractive structural features of the BIAN framework. [Pd(BIAN-IPr)(μ-Cl)Cl] 2 is the most reactive Pd( ii )-NHC precatalyst discovered to date undergoing fast activation under both an inert atmosphere and aerobic conditions. The catalyst features bulky-yet-flexible sterics that render the C-H substituents closer to the metal center in combination with rapid dissociation to monomers and strong σ-donor properties. [Pd(BIAN-IPr)(μ-Cl)Cl] 2 should be considered as a catalyst for reactions using well-defined Pd( ii )-NHCs. We report palladium-BIAN-NHC chloro dimer complex, [Pd(BIAN-IPr)(μ-Cl)Cl] 2 . This rapidly activating catalyst merges the reactive properties of palladium chloro dimers, [Pd(NHC)(μ-Cl)Cl] 2 , with the attractive structural features of the BIAN framework.