Fabricating defect-rich metal-organic frameworks via mixed linker-induced crystal transformation

Fabricating defect-rich metal-organic frameworks via mixed linker-induced crystal transformation

Defect-rich hcp UiO-66-NO was synthesized mixed linker-induced crystal transformation from fcu UiO-66-NO /NH . The defect concentration and porosity of hcp UiO-66-NO can be fine-tuned by varying the BDC-NH /BDC-NO ratio, which in turn endowed hcp UiO-66-NO with superior catalytic performance in the...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2022-06, Vol.58 (52), p.7265-7268
Hauptverfasser: Xiao, Yue, Han, Lu, Tang, Jihai, Tian, Lifang, Zhang, Zhuxiu, Zhang, Lixiong, Yang, Dong, Qiao, Xu
Format: Artikel
Sprache:eng
Schlagworte:
Alcohols
Crystal defects
Metal-organic frameworks
Nitrogen dioxide
Ring opening
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Zusammenfassung:Defect-rich hcp UiO-66-NO was synthesized mixed linker-induced crystal transformation from fcu UiO-66-NO /NH . The defect concentration and porosity of hcp UiO-66-NO can be fine-tuned by varying the BDC-NH /BDC-NO ratio, which in turn endowed hcp UiO-66-NO with superior catalytic performance in the ring-opening reaction of epoxides with alcohols.
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc00923d