“Foam Marble” Stabilized with One Type of Polymer Particle

There has been increasing interest in colloidal particles adsorbed at the air–water interface, which lead to stabilization of aqueous foams and liquid marbles. The wettability of the particles at the interface is known to play an important role in determining the type of air/water dispersed system. Foams are preferably formed using relatively hydrophilic particles, and liquid marbles tend to be formed using relatively hydrophobic particles. In this study, submicrometer-sized polystyrene particles carrying poly­(N,N-diethylaminoethyl methacrylate) hairs (PDEA–PS particles), which are synthesized by dispersion polymerization, are demonstrated to work as a particulate stabilizer for both aqueous foams and liquid marbles. A key point for the hydrophilic PDEA–PS particles to stabilize both aqueous foams and liquid marbles, which have been generally stabilized with hydrophilic and hydrophobic particles, respectively, is the wetting mode of the particles with respect to water. The flocculates of PDEA–PS particles adsorb to the air–water interface from the aqueous phase to stabilize foam in a Wenzel mode, and the dried PDEA–PS particles adsorb to the interface as aggregates from the air phase to stabilize liquid marbles in a metastable Cassie–Baxter mode. On the basis of the difference in the wetting mode, stabilization of an air-in-water-in-air multiple gas–liquid dispersed system, named “foam marble”, is realized. After the evaporation of water from the foam marble, a porous sphere is successfully obtained with pore sizes of a few tens of micrometers (reflecting the bubble sizes) and a few tens of nanometers (reflecting the gap sizes among the PDEA–PS particles).