Sources, behaviors, transformations, and environmental risks of organophosphate esters in the coastal environment: A review

The rapid growth in the global production of organophosphate esters (OPEs) has resulted in their high environmental concentrations. The low removal rate of OPEs makes the effluents of wastewater treatment plants be one of the major sources of OPEs. Due to relatively high solubility and mobility, OPEs can be carried to the coastal environment through river discharge and atmospheric deposition. Therefore, the coastal environment can be an important OPE sink. Previous studies have shown that OPEs were widely detected in coastal atmospheres, water, sediments, and even aquatic organisms. OPEs can undergo various environmental processes in the coastal environment, including adsorption/desorption, air–water exchange, and degradation. In addition, bioaccumulation of OPEs was observed in coastal biota but current concentrations would not cause significant ecological risks. More efforts are required to understand the environmental behaviors of OPEs and address resultant environmental and health risks, especially in the complicated environment. [Display omitted] •The coastal environment is an important sink of organophosphate esters (OPEs).•OPEs concentrations in the coastal environment are much higher than open ocean.•OPEs exist in various environmental media including air, seawater, and sediment.•The bioaccumulation of OPEs has been observed in coastal biota.•OPEs can be distributed remotely through atmospheric and ocean transports.