Photoinduced Polysiloxane Architectures from Spirosiloxane Precursors via Intramolecular Hydrosilylation
In this letter a method is described to synthesize new polysiloxane architectures by photoacid catalysis. An oxasilaspirocycle is designed that is able to undergo a photoacid generator catalyzed ring-opening reaction leading to either a homopolymer or to copolymers with hydroxyl-terminated polydimet...
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Veröffentlicht in: | ACS macro letters 2012-10, Vol.1 (10), p.1204-1207 |
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Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | In this letter a method is described to synthesize new polysiloxane architectures by photoacid catalysis. An oxasilaspirocycle is designed that is able to undergo a photoacid generator catalyzed ring-opening reaction leading to either a homopolymer or to copolymers with hydroxyl-terminated polydimethylsiloxane. These polymers feature a defined amount of double bonds in the backbone, which is controlled by the ratio of oxasilaspirocycle to the comonomer. The former was prepared by trispentafluorophenylborane-catalyzed intramolecular hydrosilylation of a dialkenyloxysilane with an appropriate structural motif. The UV-initiated polymerization was characterized via in situ IR spectroscopic studies to determine the rate of reaction. |
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ISSN: | 2161-1653 2161-1653 |
DOI: | 10.1021/mz300397h |