Tropane Skeleta from the Intramolecular Photocycloaddition of (4+3) Cycloadducts of Oxidopyridinium Ions and Dienes

Tropane Skeleta from the Intramolecular Photocycloaddition of (4+3) Cycloadducts of Oxidopyridinium Ions and Dienes

Easily prepared cycloadducts derived from the (4+3) cycloaddition of oxidopyridinium ions with dienes reacted intramolecularly in a [2+2] cycloaddition process to afford complex polycyclic species in which the tropane skeleton was embedded.

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Veröffentlicht in:Organic letters 2022-05, Vol.24 (19), p.3521-3525
Hauptverfasser: Fu, Chencheng, Sungnoi, Wanna, Tu, Jianzhuo, Kelley, Steven P., Harmata, Michael
Format: Artikel
Sprache:eng
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Zusammenfassung:Easily prepared cycloadducts derived from the (4+3) cycloaddition of oxidopyridinium ions with dienes reacted intramolecularly in a [2+2] cycloaddition process to afford complex polycyclic species in which the tropane skeleton was embedded.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.2c01228