Low-Thermal Expansion Zirconyl Phosphate Ceramic

The possibility of obtaining thermal-shock-resistant material in the ZrO2-P2O5 system was studied. A zirconium oxychloride salt (ZrOCl2.8H2O) and phosphoric acid (H3PO4) were used as precursors, and mixed in the ratios 1:1, 1.5:1, and 2:1. The resultant compounds were dried and sintered at different...

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Veröffentlicht in:Key engineering materials 1997-04, Vol.132-136 (2), p.829-832
Hauptverfasser: Costache, Adrian, Raut, Lucretia, Muntean, Marcela
Format: Artikel
Sprache:eng
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Zusammenfassung:The possibility of obtaining thermal-shock-resistant material in the ZrO2-P2O5 system was studied. A zirconium oxychloride salt (ZrOCl2.8H2O) and phosphoric acid (H3PO4) were used as precursors, and mixed in the ratios 1:1, 1.5:1, and 2:1. The resultant compounds were dried and sintered at different temperatures (1200 and 1300 C). The samples were characteried by XRD and SEM. The crystalline zirconyl-phosphates compounds obtained were correlated with the processing conditions. 4 refs.
ISSN:1013-9826
1662-9795
1662-9795
DOI:10.4028/www.scientific.net/KEM.132-136.829