Fractal kinetics of the oxidaton of aliphatic polyamides

Analysis of reactions kinetics in solid polymers requires a consideration of structural inhomogeneity of different levels and transport retardation of active particles peculiar to polymers. However, for multi-step reactions this problem may be only posed after sufficiently comprehensive description of their specific mechanism representing the balance of separate steps correlation. The kinetic justification of a new mechanism of aliphatic polyamides photooxidation that was completed recently makes this possible. Sufficient extending of mesaured rates diapason to the post-effect area of UV-irradiation allows to estimate correlation of homogeneous and inhomogeneous factors of this process in the context of fractal kinetic model.