Direct C–H Sulfonylimination of Pyridinium Salts

Direct C–H Sulfonylimination of Pyridinium Salts

A direct pyridinium C–H sulfonylimination has been developed for the synthesis of sulfonyl iminopyridine derivatives with high efficiency. This transformation features the direct and efficient formation of a CN bond with a high functional group tolerance under metal-free conditions. The spectroscop...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Organic letters 2022-04, Vol.24 (15), p.2821-2825
Hauptverfasser: Luo, Lihua, Tang, Juan, Sun, Rui, Li, Wenjing, Zheng, Xueli, Yuan, Maoling, Li, Ruixiang, Chen, Hua, Fu, Haiyan
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A direct pyridinium C–H sulfonylimination has been developed for the synthesis of sulfonyl iminopyridine derivatives with high efficiency. This transformation features the direct and efficient formation of a CN bond with a high functional group tolerance under metal-free conditions. The spectroscopic properties potentially enable these sulfonyl iminopyridine compounds to be useful new emitting materials.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.2c00725