Triethanolamine stabilized non-alkyl Sn4Cd4 and alkyl Sn2Cd12 oxo clusters with distinct electrocatalytic activities

Triethanolamine stabilized non-alkyl Sn4Cd4 and alkyl Sn2Cd12 oxo clusters with distinct electrocatalytic activities

Two unprecedented Sn/Cd-oxo clusters, including non-alkyltin SnII2SnIV2Cd4 and alkyltin SnIV2Cd12, have been constructed using triethanolamine and inorganic or organic tin precursors, respectively. Comparative electrocatalytic CO2 reduction experiments show that the presence of non-alkyl and variabl...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2022-04, Vol.58 (30), p.4759-4762
Hauptverfasser: Wang, Di, Guang-Hui Chen, San-Tai, Wang, Zhang, Jian, Zhang, Lei
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Clusters
Tin
Triethanolamine
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container_issue 30
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container_title Chemical communications (Cambridge, England)
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creator Wang, Di
Guang-Hui Chen
San-Tai, Wang
Zhang, Jian
Zhang, Lei
description Two unprecedented Sn/Cd-oxo clusters, including non-alkyltin SnII2SnIV2Cd4 and alkyltin SnIV2Cd12, have been constructed using triethanolamine and inorganic or organic tin precursors, respectively. Comparative electrocatalytic CO2 reduction experiments show that the presence of non-alkyl and variable-valent tin centres could greatly improve the catalytic activities.
doi_str_mv 10.1039/d2cc00574c
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Clusters
Tin
Triethanolamine
title Triethanolamine stabilized non-alkyl Sn4Cd4 and alkyl Sn2Cd12 oxo clusters with distinct electrocatalytic activities
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