Triethanolamine stabilized non-alkyl Sn4Cd4 and alkyl Sn2Cd12 oxo clusters with distinct electrocatalytic activities

Triethanolamine stabilized non-alkyl Sn4Cd4 and alkyl Sn2Cd12 oxo clusters with distinct electrocatalytic activities

Two unprecedented Sn/Cd-oxo clusters, including non-alkyltin SnII2SnIV2Cd4 and alkyltin SnIV2Cd12, have been constructed using triethanolamine and inorganic or organic tin precursors, respectively. Comparative electrocatalytic CO2 reduction experiments show that the presence of non-alkyl and variabl...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2022-04, Vol.58 (30), p.4759-4762
Hauptverfasser: Wang, Di, Guang-Hui Chen, San-Tai, Wang, Zhang, Jian, Zhang, Lei
Format: Artikel
Sprache:eng
Schlagworte:
Clusters
Tin
Triethanolamine
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Zusammenfassung:Two unprecedented Sn/Cd-oxo clusters, including non-alkyltin SnII2SnIV2Cd4 and alkyltin SnIV2Cd12, have been constructed using triethanolamine and inorganic or organic tin precursors, respectively. Comparative electrocatalytic CO2 reduction experiments show that the presence of non-alkyl and variable-valent tin centres could greatly improve the catalytic activities.
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc00574c