Visible light-driven CO2 reduction with a Ru polypyridyl complex bearing an N-heterocyclic carbene moiety

Visible light-driven CO2 reduction with a Ru polypyridyl complex bearing an N-heterocyclic carbene moiety

A novel Ru polypyridyl complex with an N-heterocyclic carbene ligand was successfully synthesised and characterised. The complex exhibited an intense absorption band in the visible-light region derived from the strong electron-donating character of the carbene ligand, and efficiently catalysed the v...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2022-04, Vol.58 (34), p.5229-5232
Hauptverfasser: Watanabe, Taito, Saga, Yutaka, Kosugi, Kento, Iwami, Hikaru, Kondo, Mio, Masaoka, Shigeyuki
Format: Artikel
Sprache:eng
Schlagworte:
Absorption spectra
Carbenes
Carbon dioxide
Ligands
Reduction
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Zusammenfassung:A novel Ru polypyridyl complex with an N-heterocyclic carbene ligand was successfully synthesised and characterised. The complex exhibited an intense absorption band in the visible-light region derived from the strong electron-donating character of the carbene ligand, and efficiently catalysed the visible light-driven CO2 reduction with the reaction rate of 36.7 h−1.
ISSN:1359-7345
1364-548X
DOI:10.1039/d2cc00657j